Detection of Hg pollution by stream sediment geochemistry in the Bisagno valley (Genoa, Italy)     

L. Marini  G. Ottonello  M. Canepa  F. Cipolli  M. Vetuschi Zuccolini 《Environmental Geology》2000,40(1-2):234-242

 Systematic stream sediment investigation in a periurban area surrounding Genoa (Italy) revealed the existence of a significant mercury anomaly localized on the main (3rd rank) bed of the Bisagno river. Statistical multivariate analysis of elemental abundances points out the anthropic nature of this contamination. Because of the well-known bioaccumulation of Hg in contaminated media, attention must be focused on the risks associated with the discovered pollution. Received: 30 November 1999 · Accepted: 22 March 2000  相似文献   

The impact of land use change and check‐dams on catchment sediment yield     

Carolina Boix‐Fayos  Joris de Vente  María Martínez‐Mena  Gonzalo G. Barberá  Víctor Castillo 《水文研究》2008,22(25):4922-4935

Extensive land use changes have occurred in many areas of SE Spain as a result of reforestation and the abandonment of agricultural activities. Parallel to this the Spanish Administration spends large funds on hydrological control works to reduce erosion and sediment transport. However, it remains untested how these large land use changes affect the erosion processes at the catchment scale and if the hydrological control works efficiently reduce sediment export. A combination of field work, mapping and modelling was used to test the influence of land use scenarios with and without sediment control structures (check‐dams) on sediment yield at the catchment scale. The study catchment is located in SE Spain and suffered important land use changes, increasing the forest cover 3‐fold and decreasing the agricultural land 2·5‐fold from 1956 to 1997. In addition 58 check‐dams were constructed in the catchment in the 1970s accompanying reforestation works. The erosion model WATEM‐SEDEM was applied using six land use scenarios: land use in 1956, 1981 and 1997, each with and without check‐dams. Calibration of the model provided a model efficiency of 0·84 for absolute sediment yield. Model application showed that in a scenario without check dams, the land use changes between 1956 and 1997 caused a progressive decrease in sediment yield of 54%. In a scenario without land use changes but with check‐dams, about 77% of the sediment yield was retained behind the dams. Check‐dams can be efficient sediment control measures, but with a short‐lived effect. They have important side‐effects, such as inducing channel erosion downstream. While also having side‐effects, land use changes can have important long‐term effects on sediment yield. The application of either land use changes (i.e. reforestation) or check‐dams to control sediment yield depends on the objective of the management and the specific environmental conditions of each area. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Enhancing RUSLE to include runoff‐driven phenomena     

Seth M. Dabney  Daniel C. Yoder  Dalmo A. N. Vieira  Ronald L. Bingner 《水文研究》2011,25(9):1373-1390

RUSLE2 (Revised Universal Soil Loss Equation) is the most recent in the family of Universal Soil Loss Equation (USLE)/RUSLE/RUSLE2 models proven to provide robust estimates of average annual sheet and rill erosion from a wide range of land use, soil, and climatic conditions. RUSLE2's capabilities have been expanded over earlier versions using methods of estimating time‐varying runoff and process‐based sediment transport routines so that it can estimate sediment transport/deposition/delivery on complex hillslopes. In this report we propose and evaluate a method of predicting a series of representative runoff events whose sizes, durations, and timings are estimated from information already in the RUSLE2 database. The methods were derived from analysis of 30‐year simulations using a widely accepted climate generator and runoff model and were validated against additional independent simulations not used in developing the index events, as well as against long‐term measured monthly rainfall/runoff sets. Comparison of measured and RUSLE2‐predicted monthly runoff suggested that the procedures outlined may underestimate plot‐scale runoff during periods of the year with greater than average rainfall intensity, and a modification to improve predictions was developed. In order to illustrate the potential of coupling RUSLE2 with a process‐based channel erosion model, the resulting set of representative storms was used as an input to the channel routines used in Chemicals, Runoff, and Erosion from Agricultural Management Systems (CREAMS) to calculate ephemeral gully erosion. The method was applied to a hypothetical 5‐ha field cropped to cotton in Marshall County, MS, bisected by a potential ephemeral gully having channel slopes ranging from 0·5 to 5% and with hillslopes on both sides of the channel with 5% steepness and 22·1 m length. Results showed the representative storm sequence produced reasonable results in CREAMS indicating that ephemeral gully erosion may be of the same order of magnitude as sheet and rill erosion. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Assessing damaged road verges as a suspended sediment source in the Hampshire Avon catchment,southern United Kingdom     

A. L. Collins  D. E. Walling  R. W. Stroud  M. Robson  L. M. Peet 《水文研究》2010,24(9):1106-1122

Diffuse sediment pollution impairs water quality, exerts a key control on the transfer and fate of nutrients and contaminants and causes deleterious impacts on freshwater ecology. A variety of catchment sediment sources can contribute to such problems. Sediment control strategies and effective targeting of mitigation options therefore require robust quantitative information on the key sources of the sediment problem at catchment scale. Recent observations by Catchment Sensitive Farming Officers (CSFO's) in England have highlighted road verges damaged and eroded by passing vehicles, particularly large farm machinery, and livestock herd movement as visually important potential sources of local sediment problems. A study was therefore undertaken to assess the relative importance of damaged road verges as a suspended sediment source in three sub‐catchments of the Hampshire Avon drainage basin, southern UK. Road verge sediment contributions were apportioned in conjunction with those from agricultural topsoils and channel banks/subsurface sources. Time‐integrating isokinetic samplers were deployed to sample suspended sediment fluxes at the outlets of two control sub‐catchments drained by the Rivers Chitterne and Till selected to characterize areas with a low road network density and limited visual evidence of verge damage, as well as the River Sem sub‐catchment used to represent areas where road verge damage is more prevalent. The findings of a sediment source fingerprinting investigation based on a combination of intermittent sampling campaigns spanning the period 22/5/02–27/4/08 suggested that the respective overall mean relative sediment contributions from damaged road verges were 5 ± 3%, 4 ± 2% and 20 ± 2%. Relative inputs from damaged road verges for any specific sampling period in the River Sem sub‐catchment were as high as 33 ± 2%. Reconstruction of historical sources in the same sub‐catchment, based on the geochemical record stored in a floodplain depth profile, suggested that the significance of damaged road verges as a sediment source has increased over the past 15–20 years. The findings provide important information on damaged road verges as a primary source of suspended sediment and imply that catchment sediment control strategies and mitigation plans should consider such verges in addition to those agricultural and channel sources traditionally taken into account when attempting to reduce sediment pressures on aquatic resources. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Assessment of intermediate fine sediment storage in a braided river reach (southern French Prealps)     

O. Navratil  C. Legout  D. Gateuille  M. Esteves  F. Liebault 《水文研究》2010,24(10):1318-1332

This paper presents a field investigation on river channel storage of fine sediments in an unglaciated braided river, the Bès River, located in a mountainous region in the southern French Prealps. Braided rivers transport a very large quantity of bedload and suspended sediment load because they are generally located in the vicinity of highly erosive hillslopes. Consequently, these rivers play an important role because they supply and control the sediment load of the entire downstream fluvial network. Field measurements and aerial photograph analyses were considered together to evaluate the variability of fine sediment quantity stored in a 2·5‐km‐long river reach. This study found very large quantities of fine sediment stored in this reach: 1100 t per unit depth (1 dm). Given that this reach accounts for 17% of the braided channel surface area of the river basin, the quantities of fine sediment stored in the river network were found to be approximately 80% of the mean annual suspended sediment yields (SSYs) (66 200 t year^?1), comparable to the SSYs at the flood event scale: from 1000 t to 12 000 t depending on the flood event magnitude. These results could explain the clockwise hysteretic relationships between suspended sediment concentrations and discharges for 80% of floods. This pattern is associated with the rapid availability of the fine sediments stored in the river channel. This study shows the need to focus on not only the mechanisms of fine sediment production from hillslope erosion but also the spatiotemporal dynamics of fine sediment transfer in braided rivers. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Creep of saturated materials as a chemically enhanced rate‐dependent damage process     

Liang Bo Hu  Tomasz Hueckel 《国际地质力学数值与分析法杂志》2007,31(14):1537-1565

Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time‐rate dependence of the resulting strain. A basic model of a combined chemo‐plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage‐generated inter‐phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

大亚湾西部海域沉积物中生物硅的含量及其分布特征          下载免费PDF全文

周鹏  李冬梅  李海涛  赵力  赵峰  郑远来  吴梅桂  余汉生 《应用海洋学学报》2019,38(1):109-117

采用2. 0 mol/dm~3Na_2CO_3溶液5h单点化学提取-硅钼蓝连续分光光度分析法分别测定了大亚湾西部海域13个表层沉积物和1个沉积物岩芯中生物硅的含量.表层沉积物和沉积物岩芯中生物硅含量占比分别为0. 69%～2. 02%和1. 24%～2. 05%,平均值分别为1. 42%和1. 60%.结果证实西大亚湾沉积物中生物硅含量水平与我国南海近岸海域基本一致.在210Pbex测年的基础上,通过分析沉积物岩芯中生物硅、有机物、无机碳等多指标,揭示近百年来大亚湾周边环境变化对海洋环境的影响,证实了上世纪80年代以来西大亚湾周边农业、海水养殖业和工业发展等人类活动加剧了该海域生态环境变化,尤其90年代核电站运行对海洋生态变化造成一定的影响.  相似文献   

Composite suspended sediment particles in river systems: their incidence,dynamics and physical characteristics     

J. C. Woodward  D. E. Walling 《水文研究》2007,21(26):3601-3614

Most of the existing data on the effective particle size characteristics of fluvial suspended sediment derive from instantaneous sampling methods that may not be representative of the overall suspended sediment loads. This presents difficulties when there is a need to incorporate effective particle size data into numerical models of floodplain sedimentation and sediment‐associated contaminant transfer. We have used a field‐based water elutriation apparatus (WEA) to assemble a large (36 flood) database on the time‐integrated nature of the effective and absolute particle size characteristics of suspended sediment in four subcatchments of the River Exe basin of southwest England. These catchments encompass a wide range of terrains and fluvial environments that are broadly representative of much of the UK and temperate, low relief northwest Europe. The WEA provides important data on the physical characteristics of composite particles that are not attainable using other methods. This dataset has allowed, for the first time, detailed interbasin comparisons of the time‐integrated particle size characteristics of suspended sediment and reliable estimates of the contribution of five effective size classes to the mean annual suspended sediment load of the study catchments. The suspended sediment load of each river is dominated by composite rather than primary particles, with, for example, almost 60% (by mass) of the sediment load of the River Exe at Thorverton transported as composite particles > 16 µm in size. All the effective size classes contain significant clay components. A key outcome of this study is the recognition that each catchment has a distinctive time‐integrated effective particle size signature. In addition, the time‐integrated effective particle size characteristics of the suspended loads in each of the catchments display much greater spatial variability than the equivalent absolute particle size distributions. This indicates that the processes producing composite particles vary significantly between these catchments, and this has important implications for our understanding of the dynamics of suspended sediment properties. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Heavy metals,polycyclic aromatic hydrocarbons and organochlorine pesticides in the surface sediments of mangrove swamps from coastal sites along the Leizhou Peninsula, South China     

TANG Yijie  FANG Zhanqiang  YU Shixiao 《海洋学报(英文版)》2008,27(1):42-53

Contents of heavy metals, polycyclic aromatic hydrocarbons （PA Hs）, dichlorodiphenyltrichloroethanes （DDTs） and hexachlorcy- clohexanes （HCHs） in surface sediments from mangrove areas of the Leizhou Peninsula were analyzed in July and November 2005. Risk assessment criteria applied by Long E R et al. （1995） and Long E D et al. （1995） （effects range low, ERL; effects range mean, ERM） of chemicals in sediments from the gulf or estuary were used to assess the potential ecological risks of heavy metals, PAHs, DDTs and HCHs to aquatic organisms in the studied area. The results indicated that the average contents of zinc, nickel, chromium, lead, copper, arsenic and mercury were （61.97 ± 55.87）, （59.99 ± 39.01 ）, （47.93 ± 28.37）, （26.64± 13.00） , （23.45 ± 41.96）, （9.32 ± 3.62）, （0.14 ± 0.18） mg/kg in dry weight in the sediment samples col- lected from five studied sites in the Leizhou Peninsula, respectively. Cadmium was not calculated due to its content being below the detection limit （ 〈 0.3 mg,/kg）. The average levels of Cr, Cu, Ni, Pb, Zn and Hg exceed their background values. The average contents of Ni were higher than ERM. The contents of PAHs in the sediments from the five studied sites were （79.78 ± 43.70） ng/g in dry weight, far lower than ERL（4 022 ng/g）. The contents of DDE, DDD and DDTs in the sediments from five studied sites were （2.60 ± 4.68）, （ 17.52 ± 27.25 ）, （27.78 ± 46.64） ng/g in dry weight respectively, clearly higher than ERL, and the average contents of DDT were （7.66 ± 15.93） ng/g in dry weight, much higher than ERM. HCHs could be detected in the sediments only from Gaoqiao sampling site, with the average contents （0.07 ± 0.08） ng/g in dry weight.  相似文献   

Distribution and sources of organochlorine pesticides in water and sediments from Daliao River estuary of Liaodong Bay,Bohai Sea (China)   总被引：1，自引：0，他引：1  

Li Tan  Mengchang HeBin Men  Chunye Lin 《Estuarine, Coastal and Shelf Science》2009

The levels of 19 kinds of organochlorine pesticides (OCPs) in the aqueous phase, suspended particulate matter (SPM), pore water and sediments from Daliao River estuary of Liaodong Bay (Bohai Sea) in northeast China were investigated to evaluate their potential pollution risks. The total OCPs concentrations in the aqueous phase, SPM, pore water and sediments were 3.7–30.1 ng l⁻¹, 4.6–52.6 ng l⁻¹, 157–830 ng l⁻¹ and 2.1–21.3 ng g⁻¹ dry weight, respectively. The concentrations of OCPs, in the Daliao River estuary, are in the mid-range, as compared to those reported in other estuaries worldwide. The distribution of HCHs and DDTs were different indicating different contamination sources. Lindane is the main type of HCH and continuing use in northeast China of ‘pure’ HCH (lindane) rather than technical HCH accounts for the source. The ratios of (DDE + DDD)/DDT in the samples indicate no recent inputs of these chemicals to the estuary.  相似文献